There are four main categories of failure modes that can occur in glass-lined equipment: mechanical, thermal, electrical, and chemical. These issues, however, can be eliminated or drastically reduced through the identification of the various types of glass failure and by asserting the best practices to avoid them.
The following information has been extracted from Materials Technology Institute's Repair and Damage Assessment for Glass-Lined Equipment, written by Sal Falcone and Bert Moniz. (More information about this book can be found on MTI’s website) These important points serve as an excellent resource for plant managers, maintenance engineers, and any other personnel who works in close contact with glass-lined equipment and systems. In this first of two posts, we’ll discuss the best practices for preventing mechanical and thermal damage.
Bad practice: Allowing a hard object heavier than 1 pound to fall from greater than 9 inches can cause glass damage.
- Padding the floor and agitator blades when working inside equipment.
- All covering open manways and nozzles during maintenance work when not in use.
Bad practice: Allowing workers to strike the outside of glass-lined vessel, leading to internal damage
- Training people not to be “bell ringers” near glass-lined equipment!
- Avoiding glass-lined vessels brushing or striking anything during rigging.
- Ensuring glass-lined equipment is clearly labeled.
Bad Practice: Impinging water pressures at greater than 2000 psi at a hose nozzle distance less than 12 in., which may cause glass damage.
- Using a filter to remove particulate matter from the water.
- Moving the water lance continuously to minimize focusing the jet in one spot.
- Protecting the manway from accidental lance contact by means of a PTFE liner.
- Avoiding water jet contact with repair areas such as plugs and patches.
Bad Practice: Allowing glass contact by solids harder than glass, which will cause general abrasion or local scratching.
- Evaluating slurries for their abrasive effect before use.
- Following strict housekeeping rules when entering and working inside glass-lined vessels
Bad practice: Collapsing bubble locally generate impact forces on glass surfaces
- If cavitation can be heard (usually a buzzing sound), adjust sparging and reduce agitator speed until the sound disappears.
- Avoiding low boiling point compounds of process fluids to be in solution.
- Operating at higher pressure.
- Using sparkers with small holes directed away from vessel sidewalls
- For condensable vapor additions, incorporating a small amount of noncondensible vapor such as nitrogen to prevent bubble collapse.
Bad Practice: Allowing glass to be crushed under excessive local compression
- Avoiding the practice of prying against a glass surface with a screw driver or other device.
- Using a flange spreader to separate flanges.
- Applying zero bending load on nozzles by supporting connected piping.
- Supporting excessive hanging weight on the bottom outlet nozzle.
- Using an approved line blinding method.
- Using approved gaskets and torque procedure.
Bad practice: Allowing glass-lined nozzles to experience bending moments greater than 100 ft-lb per inch of nozzle diameter may cause cracks in the glass.
- Ensuring piping connected to glass vessels does not result in stresses and moments on the nozzle by using stress analysis and proper alignment.
- Supporting piping and components attached to all nozzles.
- Having a short section of piping connected directly to the vessel flange, breaking the line one flange away from the Bessel first of all, and connecting the short pipe to the vessel first when reinstalling.
- Adequate saddle supports when storing, transporting, or operating horizontal vessels.
Bad Practice: Operating conditions that result in excessive vibrations are not eliminated and result in failure of internal steel members by fatigue.
- Positioning h, d, beavertail (wide eye), finger and fin baffles radially in line with agitator shaft
- Ensuring appropriate agitation for the reaction based on stress analysis and mixing requirements.
- Sizing dip tubes for process conditions.
- Locating dip tubes behind a baffle in the direction of flow.
- Designing dip tubes to be shorter than the length of nearby baffles.
- Using dip tubes for their proper purpose, not as baffles.
- Using proper sparging design when injecting steam or hot gases.
General Thermal Shock
- Making cold liquid addition onto hot glass surfaces (worst case)
- Making hot liquid addition on cold glass surfaces.
- Allowing rapid endothermic or exothermic process reactions.
- Making sure sudden temperature changes are less than T260F as conservative rule, or using the glass manufacturers’ charts to define an appropriate value.
- Using a dip tube for additives that exceed thermal shock limits.
- In critical applications, using a fast resistance-type temperature probe to gain data on temperature change.
- Programming or controlling steam addition in jacket.
- Ensuring glass thickness at convex surfaces (e.g. nozzles) does not exceed maximum requirements.
Local Thermal Shock
- Allowing hot or cold fluid to impinge on the shell (e.g., steam at jacket nozzle inlet).
- Adding steam through a sparger that allows it to impinge on the opposite wall of vessel
- Adding hot or cold fluid directly through a nozzle, allowing it to run down the wall.
- Checking jacket nozzle to ensure that the impingement baffle (deflector plate) and agitation nozzle are intact and not corroded.
- Preventing blow back (impingement from reverse flow) by means of a functioning check valve.
- Installing a vacuum breaker at the upper jacket nozzle to prevent introduction of cold water in a hot jacket
- Programming or controlling steam addition to allow gradual thermal equilibrium
- Designing the sparger to avoid direct steam impingement on glass surface.
- Always adding fluids through a dip tube or nozzle liner.
- Ensuring that absence of complete insulation does not create a local thermal shock problem.
Welding Near Glass
Bad Practice: Welding on metal near glass causes glass to shatter because of the significant rate of temperature change.
- Welding less than a four-inch long bead in any area at one time
- Allowing glass in weld areas to cool enough to be comfortable to the touch between applications of weld bead.
- Keeping air flowing in a jacket to increase cooling effect.
- Developing a repair welding procedure and qualifying welders to the procedure
- Avoiding weld spatter on glass by covering it with a blanket.
Restricted flexibility from large fillet welds
- Causing temperature differentials across large fillet welds that exist between jacketed and non-jacketed locations to transmit high stress to a glass lining.
- Allowing plugging of the outlet nozzle jacket diaphragm ring, which causes it to be excessively stiff, reduces its capability to move in response to thermal stresses.
- Conducting a thermal stress analysis if high thermal stresses are suspected.
- Blowing down sludge regularly to avoid plugging of outlet nozzle diaphragm ring.
Expansion of Steel
Bad Practice: Avoiding excessive steel expansion, which causes glass to spall.
- Preventing water from freezing in baffles or jacket (e.g. outdoor storage)
- If jacket fluid is not circulating, draining the fluid completely and venting the jacket
- For steam-jacketed units, slightly opening the blowdown valve on the strainer upstream from the trap to prevent condensate from flooding the jacket and freezing if the steam trap fails.
- Operating within temperature and pressure rating of vessel jacket.
- Venting liquid-filled thermocouple baffles to avoid pressure buildup during reaction heat-up.
Bad practice: Allowing a static charge build up in agitated non-conductive liquids or falling powder additions may lead to breakdown of glass lining.
- Assessing spark potential with non-conductive solvents and when charging powders. Reducing agitation speed.
- Adding liquids through dip tubes so that they enter below the liquid level line.
- Incorporating water or soluble additives to increase solution conductivity
- Introduction of inert gas in the vapor space (nitrogen padding) to avoid explosion.
- Using excessive spark testing voltages that exceed the capability of a glass lining.
- Conducting spark testing on thin non-stick linings used for polymer processing.
- Conducting spark testing at factory voltages of 15,000V to 20,000V.
- Conducting field testing at 50000-6000V maximum
- Conducting field testing at reduced voltages below 6000V if there is a loss of glass.
Chemical Attack - Glass
Minimum Available Glass Thickness
Bad practice: Ignorance of or failure to anticipate minimum thickness of glass required for corrosion resistance.
- Measuring glass thickness periodically for process environments that corrode glass.
- Exposing corrosion coupons in process environments that are corrosive to glass to estimate rate of attack.
Corrosion by Water
- Using pure water for boil up or dummy running.
- Cleaning a pipe with soft or deionized water and keeping it there with heat tracing on.
- Adding a small amount of acid to the water.
- Insulating and/or heating the top head for hot processes to prevent rivulets of corrosive attack of the glass.
Corrosion by Acids
Bad practice: Failing to recognize the damaging effect of hydrofluoric, phosphoric or phosphorus acids.
- Investigating the presence of damaging acids or their ions in the process.
- Making use of manufacturers’ iso-corrosion charts when selecting glass for an application
Corrosion by Alkalis
Bad Practice: Failing to recognize damaging effect of hot alkali solutions on glass
- Anticipating the severity of alkali conditions in process.
- Always adding alkalis via dip tubes.
Corrosion by Salts
Bad Practice: Failing to recognize the potentially damaging effect of specific types of ions produced by salt solution.
Good practice: Anticipating effects of acid fluorides, chlorides, plus lithium, magnesium and aluminum.
Chemical Attack – Repair Materials
Degradation of Tantalum Patches and Plugs
Bad Practice: Allowing situations where tantalum may corrode or embrittle
- Checking for hydrogen damage of tantalum plugs and patches, and that they are not loose.
- Weld a platinum spot on a tantalum patch to prevent hydrogen embrittlement in certain applications.
Attack of Furan or Silicate Cements
Bad Practice: Using furan or silicate cements in process environments that attack it.
Good practice: Respecting the limitations and curing requirements of furan/silicate cement.
Damage to PTFE components
Bad practice: Failure to appreciate the physical capabilities of PTFE-protective liners or boots
Good practice: Replacing materials early enough, before underlying glass is damaged.
Chemical Attack - Steel
Corrosion from External Spills or Wet Insulation
- Allowing corrosive chemicals or powders to spill on external surface from sloppy charging of constituents to vessel.
- Allowing insulation to remain wet from hose-down or chemical spills.
- Maintaining leak-free flange makeup practices
- Neutralizing any are of acid or acid powder spill before washing and repainting
- Maintaining caulking in thermal insulation jacketing.
- Applying an immersion-grade coating to the top head region, including nozzles, instead of a non-immersion grade paint.
- Checking top head when spills are suspected and restore paint coating if rusting is suspected.
- Using dump chutes when loading corrosives through the manway.
- Applying stainless steel sheathing over insulation.
Damage from Chemical Cleaning of Jacket
Bad Practice: Allowing excessive corrosion of the vessel shell from acidic cleaning of the jacket, which can lead to spalling of glass.
Good Practice: Using a neutral cleaning agent, respecting longer time required for cleaning.
Flange Face Spalling
Bad Practice: Allowing flanges to leak and cause flaking of glass on the gasket face.
- Using an effective flange make-up procedure to ensure a tight seal and no process leakage.
- Using alloy 600 overlay on flange face beneath glass lining.